Разработка различных типов тонкопленочной электроники: гибридных и неорганических перовскитных солнечных батарей, фотодетекторов,  устройств памяти на основе органических полевых транзисторов

Соавтор более чем 80 статей в высокорейтинговых международных и российских научных журналах. Сделала более 50 устных и приглашенных докладов на международных научных конференциях и школах. Руководила двумя грантами РФФИ, тремя проектами Министерства науки и высшего образования РФ и тремя грантами Российского научного фонда, два из них находятся в процессе реализации.

Была руководителем >20 дипломных работ студентов и 2 аспирантов.

Индекс Хирша h=22 (Web of Science), h=22 (Scopus), h=22 (Google Scholar)

Соавтор более чем 80 статей в высокорейтинговых международных и российских научных журналах.

Избранные публикации:

1. M. K. Kuznetsov, N. A. Emelianov, D. V. Korchagin, G. V. Shilov, S. M. Aldoshin, P. A. Troshin and L. A. Frolova, Photostability of CsPbI₂Br-based Perovskite Solar Cells through suppression of the phase segregation using a zwitterionic additive. Sustain. Energy Fuels, 2022, DOI:10.1039/D2SE00450J.
2. O. Kraevaya, A. Latypova, A. A. Sokolova, A. A. Seleznyova, N. A. Emelianov, N. A. Slesarenko, V. Y. Markov, L. Frolova and P. Troshin, Oxidative polymerization of triarylamines: a promising route to low-cost hole transport materials for efficient perovskite solar cells. Sustain. Energy Fuels, 2022, DOI:10.1039/D2SE00492E.
3. L. A. Frolova, Y. Furmansky, A. F. Shestakov, N. A. Emelianov, P. A. Liddell, D. Gust, I. Visoly-Fisher and P. A. Troshin, Advanced Nonvolatile Organic Optical Memory Using Self-Assembled Monolayers of Porphyrin–Fullerene Dyads. ACS Appl. Mater. Interfaces, 2022, 14, 15461–15467.
4. E. Komissarova, S. A. Kuklin, A. Maskaev, A. Latypova, P. Kuznetsov, N. A. Emelianov, S. L. Nikitenko, I. Martynov, I. E. Kuznetsov, A. V. Akkuratov, L. Frolova and P. Troshin, Novel benzodithiophene-TBTBT copolymers: synthesis and investigation in organic and perovskite solar cells. Sustain. Energy Fuels, 2022, DOI:10.1039/D2SE00463A.
5. N. A. Emelianov, V. V. Ozerova, I. S. Zhidkov, D. V. Korchagin, G. V. Shilov, A. L. Litvinov, E. Z. Kurmaev, L. A. Frolova, S. M. Aldoshin and P. A. Troshin, Nanoscale Visualization of Photodegradation Dynamics of MAPbI₃ Perovskite Films J. Phys. Chem. Lett., 2022, 13, 2744–2749.
6. M. M. Elnaggar, L. G. Gutsev, N. A. Emelianov, P. M. Kuznetsov, L. A. Frolova, S. M. Aldoshin and P. A. Troshin, Molecular Engineering of Polytriarylamine-Based Hole-Transport Materials for p–i–n Perovskite Solar Cells: Methyl Groups Matter. ACS Appl. Energy Mater. 2022, 5, 5388–5394.
7. A. F. Latypova, N. A. Emelianov, D. O. Balakirev, P. K. Sukhorukova, N. K. Kalinichenko, P. M. Kuznetsov, Y. N. Luponosov, S. M. Aldoshin, S. A. Ponomarenko, P. A. Troshin and L. A. Frolova, Design Principles for Organic Small Molecule Hole-Transport Materials for Perovskite Solar Cells: Film Morphology Matters. ACS Appl. Energy Mater., 2022, 5, 5395–5403.
8. A. Elakshar, S. Tsarev, P. M. Rajanna, M. Tepliakova, L. Frolova, Y. G. Gladush, S. M. Aldoshin, P. A. Troshin and A. G. Nasibulin, Surface Passivation for Efficient Bifacial HTL-free Perovskite Solar Cells with SWCNT Top Electrodes. ACS Appl. Energy Mater., 2021, 4, 13395–13400.
9. I. S. Zhidkov, A. F. Akbulatov, L. N. Inasaridze, A. I. Kukharenko, L. A. Frolova, S. O. Cholakh, C.-C. Chueh, P. A. Troshin and E. Z. Kurmaev, Influence of Oxygen Ion Migration from Substrates on Photochemical Degradation of CH₃NH₃PbI₃ Hybrid Perovskite. Energies, 2021, 14, 5062.
10. A. F. Akbulatov, M. I. Ustinova, G. V. Shilov, N. N. Dremova, I. S. Zhidkov, E. Z. Kurmaev, L. A. Frolova, A. F. Shestakov, S. M. Aldoshin and P. A. Troshin, Temperature Dynamics of MAPbI₃ and PbI₂ Photolysis: Revealing the Interplay between Light and Heat, Two Enemies of Perovskite Photovoltaics. J. Phys. Chem. Lett., 2021, 12, 4362–4367.
11. L. A. Frolova, L. G. Gutsev, B. R. Ramachandran, N. N. Dremova, S. M. Aldoshin and P. A. Troshin, Exploring CsPbI₃ – FAI alloys: Introducing low-dimensional Cs₂FAPb₂I₇ absorber for efficient and stable perovskite solar cells. Chem. Eng. Sci., 2021, 426, 131754
12. A. F. Akbulatov, M. I. Ustinova, L. Gutsev, S. A. Tsarev, N. N. Dremova, I. Zhidkov, S. Yu. Luchkin, B. R. Ramachandran, L. A. Frolova, E. Z. Kurmaev, K. J. Stevenson, S. M. Aldoshin, P. A. Troshin. When iodide meets bromide: halide mixing facilitates light-induced decomposition of perovskite absorber films. Nano Energy, 2021, 86, 106082
13. L. A. Frolova, S. Yu. Luchkin, Y. Lekina, S. A. Tsarev, I. Zhidkov, E. Z. Kurmaev, Z. X. Shen, K. J. Stevenson, S. M. Aldoshin, P. A. Troshin. Reversible Pb²⁺/Pb⁰ and I^-/I₃^- redox chemistry drives the light-induced phase segregation in all-inorganic mixed halide perovskites. Adv. Energy Mater., 2021, 11, 2002934
14. I. S. Zhidkov, D. W. Boukhvalov, A. F. Akbulatov, L. A. Frolova, L. D. Finkelstein, A. I. Kukharenko, S. O. Cholakh, C-C. Chueh, P. A. Troshin, E. Z. Kurmaev. XPS spectra as a tool for studying photochemical and thermal degradation in APbX₃ hybrid halide perovskites. Nano Energy, 2021, 79, 105421
15. V. V. Ozerova, I. S. Zhidkov, A. Boldyreva, N. N. Dremova, N. A. Emelianov, G. V. Shilov, L. A. Frolova, E. Z. Kurmaev, A. Y. Sukhorukov, S. M. Aldoshin and P. A. Troshin, Spectacular Enhancement of the Thermal and Photochemical Stability of MAPbI₃ Perovskite Films Using Functionalized Tetraazaadamantane as a Molecular Modifier. Energies, 2021, 14, 669.
16. M. I. Ustinova, M. M. Mikheeva, G. V. Shilov, N. N. Dremova, L. A. Frolova, S. M. Aldoshin, K. J. Stevenson, P. A. Troshin. Partial substitution of Pb²⁺ in CsPbI₃ as an efficient strategy to design fairly stable all-inorganic perovskite formulations. ACS Appl. Mater. Interfaces, 2021, 13, 5184–5194
17. I. V. Klimovich, A. V. Zhilenkov, L. I. Кuznetsova, L. A. Frolova, O. R. Yamilova, S. I. Troyanov, K. A. Lyssenko, P. A. Troshin. Novel functionalized indigo derivatives for organic electronics. Dyes and Pigments, 2021, 186, 108966
18. L. A. Frolova, A. I. Davlethanov, N. N. Dremova, A. F. Akbulatov, E. Z. Kurmaev, S. M. Aldoshin, K. J. Stevenson, I. Zhidkov, P. A. Troshin. Efficient and Stable MAPbI₃-based Perovskite Solar Cells Using Polyvinylcarbazole Passivation. J. Phys. Chem. Lett., 2020, 11, 16, 6772–6778
19. M. M. Tepliakova, A. N. Miheeva, L. A. Frolova, A. G. Boldyreva, A. Elakshar, A. V. Novikov, S. A. Tsarev, M. I. Ustinova, O. R. Yamilova, A. G. Nasibullin, S. M. Aldoshin, K. J. Stevenson, P. A. Troshin. Incorporation of vanadium (V) oxide in hybrid hole transport layer enables long-term operational stability of perovskite solar cells. J. Phys. Chem. Lett., 2020, 11, 5563–5568
20. A. G. Boldyreva, L. A. Frolova, I. S. Zhidkov, L. G. Gutsev, E. Z. Kurmaev, B. R. Ramachandran, V. G. Petrov, K. J. Stevenson, S. M. Aldoshin and P. A. Troshin, Unravelling the Material Composition Effects on the Gamma Ray Stability of Lead Halide Perovskite Solar Cells: MAPbI₃ Breaks the Records. J. Phys. Chem. Lett., 2020, 11, 2630–2636.
21. A. F. Akbulatov, L. A. Frolova, N. N. Dremova, I. Zhidkov, V. M. Martynenko, S. A. Tsarev, S. Y. Luchkin, E. Z. Kurmaev, S. M. Aldoshin, K. J. Stevenson and P. A. Troshin, Light or Heat: What Is Killing Lead Halide Perovskites under Solar Cell Operation Conditions? J. Phys. Chem. Lett., 2020, 11, 333–339.
22. S. Tsarev, I. K. Yakushchenko, S. Y. Luchkin, P. M. Kuznetsov, R. S. Timerbulatov, N. N. Dremova, L. A. Frolova, K. J. Stevenson and P. A. Troshin, A new polytriarylamine derivative for dopant-free high-efficiency perovskite solar cells. Sustainable Energy & Fuels, 2019, 3, 2627–2632.
23. D. D. Dashitsyrenova, A. G. Lvov, L. A. Frolova, A. V. Kulikov, N. N. Dremova, V. Z. Shirinian, S. M. Aldoshin, M. M. Krayushkin and P. A. Troshin, Molecular structure–electrical performance relationship for OFET-based memory elements comprising unsymmetrical photochromic diarylethenes. J. Mater. Chem. C, 2019, 7, 6889–6894.
24. L. A. Frolova, Q. Chang, S. Yu. Luchkin, D. Zhao, A. F. Akbulatov, N. N. Dremova, A. V. Ivanov, E.E. M. Chia, K. J. Stevenson and P. A. Troshin. Efficient and stable all-inorganic perovskite solar cells based on nonstoichiometric Cs_xPbI₂Br_x (x > 1) alloys. J. Mater. Chem. C, 2019, 7, 5314-5323.
25. S. A. Adonin, L.A. Frolova, M. N. Sokolov,G. V. Shilov,. D. V. Korchagin, V. P. Fedin, S. M. Aldoshin, K. J. Stevenson, P. A. Troshin, Antimony (V) complex halides: lead-free perovskite-like materials for hybrid solar cells. Adv. Energ. Mater. 2018, 1701140, featured with cover page
26. L. A. Frolova, D. V. Anokhin, A. A. Piryazev, S. Yu. Luchkin, N. N. Dremova, P. A. Troshin, Exploring the Photovoltaic Performance of All-Inorganic Ag₂PbI₄/PbI₂ Blends. J. Phys. Chem. Lett. 2017, 8, 1651−1656
27. L. A. Frolova, D. V. Anokhin, A. A. Piryazev, S. Yu. Luchkin, N. N. Dremova, K. J. Stevenson and P. A. Troshin. Highly efficient all inorganic planar heterojunction perovskite solar cells produced by thermal co-evaporation of CsI and PbI₂. J. Phys. Chem. Lett. 2017, 8, 67−72.
28. A. F. Akbulatov, L. A. Frolova, M. P. Griffin, I. R Gearba,  A. Dolocan, D. A. Vanden Bout, S. Tsarev, E. A. Katz, A. F. Shestakov, K. J. Stevenson, P. A. Troshin. Effect of electron-transport material on light-induced degradation of inverted planar junction perovskite solar cells. Adv. Energ. Mater. 2017, 7, 1700476
29. A. F. Akbulatov, S. Luchkin, L. A. Frolova, N. N. Dremova, K. J. Stevenson, P. A. Troshin. Probing the intrinsic thermal and photochemical stability of the hybrid and inorganic lead halide based perovskites. J. Phys. Chem. Lett. 2017, 8, 1211–1218
30. S. Yu. Luchkin, A. F. Akbulatov, L. A. Frolova, P.A. Troshin, K. J. Stevenson, Spatially-resolved Nanoscale Measurements of the Grain Boundary Enhanced Photocurrent in the Inorganic CsPbBr3 Perovskite Films. Sol. Energ. Mater. Sol. Cells. 2017, 171, 205-21
31. S.Yu. Luchkin, A. F. Akbulatov, L. A. Frolova, M. P. Griffin, A. Dolocan, I. R Gearba, D. A. Vanden Bout, P. A. Troshin, K. J. Stevenson, Reversible and Irreversible Electric Field Induced Morphological and Interfacial Transformations of Hybrid Lead Iodide Perovskites. ACS App. Mater. Interfaces.  2017, 9, 33478–33483
32. L. I. Leshanskaya, I. V. Klimovich, D. D. Dashitsyrenova, L. F. Frolova, E. S. Ershova, V. A. Sergeeva, V. Yu. Tabakov, S. V. Kostyuk and P. A. Troshin. Dibenzoindigo: a nature-inspired biocompatible semiconductor material for organic electronics. Adv. Opt. Mater. 2017, 5, 1601033 (Impact Factor 6.87), featured with cover page
33. I. E. Kuznetsov, D. K. Susarova, L. A. Frolova, A. S. Peregudov, A. F. Shestakov, S. I. Troyanov, K. J. Stevenson and P. A. Troshin, Chem. Comm., 2017, 53, 4830–4833
34. А. F. Akbulatov, L. A. Frolova, D. V. Anokhin, K. L. Gerasimov, N. N. Dremova, P. A. Troshin. Hydrazinium-loaded perovskite solar cells with enhanced performance and stability. J. Mater. Chem. A. 2016, 4, 18378–18382. (Impact Factor 8.262) featured with cover page
35. L. A. Frolova, D. V. Anokhin, K. L. Gerasimov, N. N. Dremova, and P. A. Troshin. Exploring the Effects of the Pb²⁺ Substitution in MAPbI3 on the Photovoltaic Performance of the Hybrid Perovskite Solar Cells. J. Phys. Chem. Lett., 2016, 7 (21), 4353–4357.
36. L.A. Frolova, N. N. Dremova, P. A. Troshin. Chemical origin of the p-type and n-type doping effects in the hybrid methylammonium - lead iodide (MAPbI₃) perovskite solar cells. Chem. Comm. 2015, 51, 14917-14920
37. L.A. Frolova, A. A. Rezvanova, V. Z. Shirinian, A. G. Lvov, A. V. Kulikov, M. M. Krayushkin, P. A. Troshin. OFET-based memory devices operating via optically and electrically modulated charge separation between the semiconductor and 1,2-bis(hetaryl)ethene dielectric layers. Adv. Elec. Mater., 2016, 2, 1500219
38. L. A. Frolova, P. A. Troshin, D. K. Susarova, A. V. Kulikov, N. A. Sanina, S. M. Aldoshin. Photoswitchable organic field effect transistors and memory elements comprising interfacial photochromic layer. Chem. Comm., 2015, 51, 6230-6132
39. L. A. Frolova, N. P. Piven, D. K. Susarova, A. V. Akkuratov, S. D. Babenko, P.A. Troshin. ESR spectroscopy for monitoring photochemical and thermal degradation of conjugated polymers used as electron donor materials in organic bulk heterojunction solar cells. Chem. Comm., 2015, 51, 2242-2244
40. L. A. Frolova, A. A. Rezvanova, B. S. Lukyanov, N. A. Sanina, P. A. Troshin, S. M. Aldoshin, Rewritable and read-only non-volatile optical memory elements using photochromic spiropyran-based salts as light-sensitive materials. J. Mater. Chem. C., 2015, 3, 11675-11680
41. A.V. Akkuratov, D.K. Susarova, A. Kozlov, D.V. Novikov, Y.L. Moskvin, L.A. Frolova, M.S. Pchenitchnikov, P.A. Troshin. Design of (X-DADAD)_n type copolymers with improved optoelectronic properties for bulk heterojunction organic solar cells. Macromolecules, 2015, 48 (7), 2013-2021
42. D.K. Susarova, N.P. Piven, A.V. Akkuratov, L.A. Frolova, S.A. Ponomarenko, S.D. Babenko, P.A. Troshin. ESR spectroscopy as a powerful tool for probing the quality of conjugated polymers designed for photovoltaic applications. Chem. Comm. 2015, 51, 2239-2241
43. L. Frolova, N. Lyskov, Yu. Dobrovolsky.  Nanostructured Pt/SnO₂-SbO_x-RuO₂ electrocatalysts for direct alcohol fuel cells. Solid State Ionics. 2012, 225, 92-98  

Книги и монографии

1. Organic and hybrid nanomaterials: production, research, application: monograph / ed. V.F. Razumova, M.V. Klyueva. Eds. Ivanovo: ISU, 2021. 368 p. (Chapter 1. Perovskite solar batteries: current research status and prospects (A. F. Akbulatov, L. A. Frolova, P. A. Troshin)
2. Yu. A. Dobrovolskii, L.A. Frolova, A.V. Arsatov, J. Zhao. Catalysts for low temperature fuel cells. in "Organic and Hybrid Nanomaterials", V.F. Razumov, M.V. Klyuyev Eds. Ivanovo, 2009, pp. 226-272.
3. L.A. Frolova, E.V. Gerasimov, Y.A. Dobrovolsky. "Electrocatalysis in electrochemical power sources." Ed. Yu. A. Dobrovolski, Chernogolovka, 2011, 60 pp.
4. Y.A. Dobrovolsky, V.E. Guterman, N.V. Smirnov, N.V. Lyskov, L.A. Frolova, A.B. Kuriganova. Textbook for students “Electrochemical energy storage and converters devices», Novocherkassk, 2012. 76 pp.

​Патенты

4 полученных патента РФ и 4 заявки на патенты в процессе рассмотрения